全文获取类型
收费全文 | 2721篇 |
免费 | 433篇 |
国内免费 | 783篇 |
专业分类
测绘学 | 55篇 |
大气科学 | 148篇 |
地球物理 | 597篇 |
地质学 | 2029篇 |
海洋学 | 498篇 |
天文学 | 4篇 |
综合类 | 130篇 |
自然地理 | 476篇 |
出版年
2024年 | 11篇 |
2023年 | 37篇 |
2022年 | 94篇 |
2021年 | 102篇 |
2020年 | 129篇 |
2019年 | 139篇 |
2018年 | 130篇 |
2017年 | 153篇 |
2016年 | 127篇 |
2015年 | 166篇 |
2014年 | 186篇 |
2013年 | 194篇 |
2012年 | 157篇 |
2011年 | 198篇 |
2010年 | 162篇 |
2009年 | 218篇 |
2008年 | 198篇 |
2007年 | 170篇 |
2006年 | 245篇 |
2005年 | 187篇 |
2004年 | 158篇 |
2003年 | 127篇 |
2002年 | 96篇 |
2001年 | 94篇 |
2000年 | 88篇 |
1999年 | 83篇 |
1998年 | 56篇 |
1997年 | 38篇 |
1996年 | 38篇 |
1995年 | 22篇 |
1994年 | 28篇 |
1993年 | 24篇 |
1992年 | 15篇 |
1991年 | 16篇 |
1990年 | 20篇 |
1989年 | 6篇 |
1988年 | 4篇 |
1987年 | 4篇 |
1986年 | 4篇 |
1985年 | 5篇 |
1984年 | 2篇 |
1980年 | 2篇 |
1979年 | 1篇 |
1977年 | 1篇 |
1976年 | 2篇 |
排序方式: 共有3937条查询结果,搜索用时 109 毫秒
31.
32.
33.
This paper studies the adsorption isotherm curves of four amino acids (glyucine,aspartic acid,glutamic acid and lysine)and the effects of existences of different concentrations of Cu(Ⅱ) on them.Both the adsorption isotherm of the amino acids on the kaolinite and that when the copper ion Cu(Ⅱ) exists belong to the Langmuir type.The slopes of these adsorption isotherm increase with the increasing concentrations of Cu(Ⅱ) added.It can be explained in terms of formation of the type(Ⅰ) ternary surface complexes in these systems.The regular pattern of the effects of copper ion Cu(Ⅱ) on the adsorption isotherm of amino acids on the kaolinite is identical with that of its effects on the exchange and adsorption percentage E(%)-pH on the kaolinite in the same system. 相似文献
34.
A novel method for prediction of the load carrying capacity of a corroded reinforced concrete beam (CRCB) is presented in the paper. Nine reinforced concrete beams, which had been working in an aggressive environment for more than 10 years, were tested in the laboratory. Comprehensive tests, including flexural test, strength test for corroded concrete and rusty rebar, and pullout test for bond strength between concrete and rebar, were condueted. The flexural test results of CRCBs reveal that the distribution of surface cracks on the beams shows a fractal behavior. The relationship between the fractal dimensions and mechanical properties of CRCBs is then studied. A prediction model based on artificial neural network (ANN) is established by the use of the fractal dimension as the corrosion index, together with the basic intbrmation of the beam. The validity of the prediction model is demonstrated through the experimental data, and satisfactory resuits are achieved. 相似文献
35.
36.
研究pH和Ca(Ⅱ)对砷酸根在海水与NaCl介质中对水合氧化物和粘土矿物上交换吸附的影响:(1)在酸性条件下和海水及NaCl介质中,砷酸根在针铁矿上的交换率E(%)—pH曲线呈平顶峰型、在δ-MnO呈峰型、在粘土上分别呈双峰型和肩峰型。这是砷酸根存在多种形式与固体表面发生离子/配位子交换以及介质中阴离子竞争交换吸附共同作用的结果。(2)在碱性条件下的海水介质中,砷酸根与水合氧化物和粘土矿物的E(%)—pH曲线都呈V型,这是因为生成了具有一定结构的液—固界面三元络合物之故。(3)在NaCl介质中,Ca加入起促进作用,再次证明液—固界面三元络合物生成机理与V型曲线的内在关系 相似文献
37.
沉积物对磷酸盐的吸附与释放 总被引:3,自引:0,他引:3
本实验研究黄河口水文站沉积物对黄河水磷的吸附释放过程和东海111号站位沉积物对海水磷的吸附释放过程。并摸拟黄河沉积物在海水中磷的吸附释放过程。结果表明:底沉积物对磷的吸附相当迅速,无论是河泥还是海泥在24h内均能达到吸附平衡。吸附量与沉积物的量和水中原有磷的浓度有关,在不同的pH条件下,沉积物对磷的吸附是有显著差别的 相似文献
38.
采用新极谱技术(1.5次微分)的阳极溶出伏安滴定方法测定天然海水的铜络合容量和条件稳定常数。对测试条件、EDTA回收率和有关问题进行了探讨。青岛近岸水样的九次平行测定表明,铜的表现络合容量为3.01×10~(-7)mol/dm~3,条件稳定常数为7.34×10~7,相对标准偏差分别为9.2%和13.8%。 相似文献
39.
40.
Distribution of dissolved species and suspended particulate copper in an intertidal ecosystem affected by copper mine tailings in Northern Chile 总被引:1,自引:0,他引:1
The coastline near Chañaral in Northern Chile is one of the most highly Cu-contaminated zones in the world due to discharges from mining activities for more than 60 years. The speciation of Cu has been studied to determine the importance of organic complexation in highly contaminated areas, and to assess the likely physiological impacts of Cu on marine organisms. Dissolved Cu concentrations of up to 500 nM were measured, completely saturating organic ligands and leading to free Cu2+ concentrations in excess of 10− 8 M. These values are higher than those reported in any other marine environment, and because they occur over an extensive area, provide a unique opportunity to study the effects of Cu on marine ecosystems and to see how Cu behaves when its speciation is predominantly inorganic. We found strong gradients in free Cu2+ between Chañaral and adjacent areas with lower Cu, where speciation is dominated by organic complexation. There is also a significant increase in the partitioning of Cu onto suspended particles in the contaminated areas, consistent with previous studies that showed that organic ligands stabilize Cu in the dissolved phase, whilst “excess” Cu is rapidly scavenged. Those high dissolved Cu concentrations persist in spite of solid phase partitioning and advective processes along this open-ocean coastline, suggesting that Cu inputs into the system are still very large. Measurements were made using anodic stripping voltammetry with a thin mercury film coated with Nafion, which previous workers have shown can mitigate ambiguity in the data arising from inadvertent reduction of organic complexes. Our findings suggest that this is a useful methodology for contaminated systems. 相似文献